No, there's no way to do that. After all, any book that you send to your Kindle is always going to be more recent than the book you're currently reading. It has nothing to do with the way you send books to your Kindle; you'll see the same no matter how they get there.
I tend to toggle between "Recent" and "Author" sort on my home screen. "Recent" to quickly open a book I'm currently reading. "Author" when I've finished a book and want to browse my library to choose the next one to read.
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